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 Birefringent Crystals

YVO4
a-BBO
Calcite


 YVO 4
Undoped YVO 4 crystal is widely used in many beam displace online_orderings because of its large birefringence. It also has good physical and favorable mechnical properties than thers birefringent crystals, which make YVO 4 well suited for compact fiber optical components, such as isolators, circulators and interleaver etc.

Capabileties:
YVO 4: T% vs Wavelength
1) Diameter : max. 25mm

 
2) Length: max. 30mm
3) Surface Quality: better than 2 0/10 scratch/dig Per MIL-0-13830A
4) Beam Deviation: <3 arc min
5) Optical Axis Orientation: +/-0.2°
6) Flatness: < l /4 @633nm
7) Transimission Wavfront Distortion: <l /2 @633nm
8) Coating: upon customer's Specification

Physical and Optical Properties
Transparency Range 400~5000nm
Crystal Symmetry Zircon tetragonal, space group D4h
Crystal Cell A=b=7.12 °, c=6.29 °
Density 4.22 g/cm 2
Hygroscopic Susceptibility Non-hygroscopic
Mohs Hardness 5 glass like
Thermal Optical Coefficient Dn a /dT=8.5x10 -6 /K; dn c /dT=3.0x10 -6 /K
Thermal Conductivity Coefficient ||C: 5.23 w/m/k; ⊥C:5.10w/m/k
Crystal Class Positive uniaxial with no=na=nb, ne=nc
Refractive Indices, Birefringence( D n=ne-no) and Walk-Off Angle at 45 deg(ρ) No=1.9929, ne=2.2154, D n=0.2225, ρ=6.04°, at 630nm
No=1.9500, ne=2.1554, D n=0.2054, ρ=5.72°, at 1300nm
No=1.9447, ne=2.1486, D n=0.2039, ρ=5.69°, at 1550nm
Sellmeier Equation ( l in m m)

n o 2 =3.77834+0.069736/(l2 -0.04724)-0.0108133l2

n e 2 =4.5905+0.110534/(l2 -0.04813)-0.0122676 l2


a-BBO

High temperature phase of BaB 2 O 4 is an excellent birefringent crystal; it is characterized by large birefringent coefficient and wide transmission window from 189nm to 3500nm, particularly it is suitable to make the high power UV polarizer, due to its unique UV transparency and good mechanical properties.

The physical, chemical, thermal and optical properties of a -BBO crystals are similar to those of b -BBO, for instant high optical homogeneity(better than 1x10-6/cm), extremely low absorption in the UV to IR range (<0.5% from 300-2300nm), low hygroscopic susceptibility, high damage threshold. However, the nonlinear optical properties of a -BBO is vanished due to the centric symmetry with its crystal structure.

Capabilities:

1) Diameter : max 40~50mm

a -BBO: T% vs Wavelength
2) Length: max 25~35mm
3) Surface Quality: better than 20/10 scratch/dig Per MIL-0-13830A
4) Beam Deviation: <3 arc min
5) Optical Axis Orientation: +/-0.5°
6) Flatness: < l/4 @633nm
7) Transimission Wavfront Distortion: <l/2 @633nm
8) Coating: upon customer's specification

Physical and Optical Properties:
Transparency Range 189-3500nm
Density 3.85g/cm3
Therm-Optic Coefficients dn o / dT = -9.3 X 10 -6 / °C
dn e / dT = -16.6.3 X 10 -6 / °C
Optical Homogeneity Δn≈10-6/cm
Damage Threshold 1 GW/cm2 at 1064nm500 MW/com2 at 532nm
Hygroscopic Susceptibility Low
Thermal Expansion Coefficients
(25℃--900℃)
aa = 4 X 10 -6 / K
ac = 4 X 10 -6 / K
Linear Absorption Coefficients a<0.005cm -1 from 300nm to 2300nm
Refractive Indices, Birefringence
(Δn=ne-no) and Walk-Off Angle at 45℃(ρ)
ne=1.58462, no=1.65790, Δn=-0.073282; ρ=-4.9532o at 1064nm
ne=1.60206, no=1.67755, Δn=-0.075491; ρ=-5.0407o at 532nm
ne=1.67190, no=1.76171, Δn=-0.089805; ρ=-5.6926o at 266nm

Calcite

Calcite is a natural crystal that has high birefringence, wide spectral transmission and availability in reasonably sized rhombs. It's a negative uniaxial crystals and mostly used as visible and near IR polarizers.

Capabilities:

1) Diameter : max 30~40mm

Calcite: T% vs Wavelength
2) Length: max 25~35mm
3) Surface Quality: better than 20/10 scratch/dig Per MIL-0-13830A
4) Beam Deviation: <3 arc minutes
5) Optical Axis Orientation: +/-0.5°
6) Flatness: < l/4 @633nm
7) Transimission Wavfront Distortion: < l/2 @633nm
8) Coating: upon customer's specification


Notes
As the susceptibility is low so that it's easy to moisture,it's difficult to achieve excellent optical quality due to low hardness.

Physical and Optical Properties:
Transparency Range 350~2300nm
Partical Shape Crystalline rhombihedral
Density 2.7 g/cm 3
Hygroscopic Susceptibility Low susceptibility to moisture
Mohs Hardness 3
Thermal Expansion Coefficient a a=24.39x10 -6 /k; a c=5.68x10 -6 /k
Crystal Class Negative uniaxial with no=na=nb, ne=nc
Refractive index, birefringence(Δ=ne-no) and walk-off angle at 45°C (ρ) n o =1.6557, n e =1.4852
Δn=-0.1705, ρ= 6.20° @ 630nm
n o =1.6629, n e =1.4885
Δn =-0.1705, ρ= 6.20° @ 1300nm
Sellmeier Equation n o 2 =2.69705+0.0192064/(λ 2 -0.01820)-0.0151624λ 2
n e 2 =2.18438+0.0087309/(λ 2 -0.01018)-0.0024411λ 2

 

 

 

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